H2O-enhanced CO2 transport through a proton conducting ceramic- molten carbonate dual-phase membrane

نویسندگان

چکیده

High-temperature membranes for CO2 transport and separation has attracted significant interest from academia industries due to their potential mitigate the emissions of ultimately global warming/climate change. In this study, we report a dual-phase membrane fabricated porous proton conducting BaZr0.8Y0.2O3-δ (BZY) matrix eutectic mixture Li2CO3–Na2CO3 (denoted as MC). The exhibits high permeation flux density in range 550–750 °C both dry wet conditions. Through microstructural optimization, 0.34 mL ⋅ cm−2 min−1 at 650 0.53 750 have been achieved with an 0.8 mm thick BZY-MC containing 52% porosity 50%CO2–N2 feed gas. is attributed synergistic effects microstructure, MC loading bulk conductivity BZY. addition, also demonstrate positive effect H2O permeate side on proposed reasonable mechanism explain H2O-enhanced density. With 3% H2O-added into sweeping gas, 30% enhancement good stability over 250 h °C.

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

An asymmetric tubular ceramic-carbonate dual phase membrane for high temperature CO2 separation.

For the first time, a tubular asymmetric ceramic-carbonate dual phase membrane was prepared by a centrifugal casting technique and used for high temperature CO2 separation. This membrane shows high CO2 permeation flux and permeance.

متن کامل

CO2‐Tolerant SrFe0.8Nb0.2O3−δ−Carbonate Dual-Phase Multichannel Hollow Fiber Membrane for CO2 Capture

Ceramic−carbonate dual-phase membranes have attracted a lot of attention because of the emission of CO2 and environmental problems. In this study, a dense SrFe0.8Nb0.2O3−δ−carbonate dual-phase multichannel hollow fiber membrane has been successfully prepared via a phase inversion−sintering technique and impregnation. The morphology, crystal structure, phase stability, breaking load, and CO2 per...

متن کامل

Molten Carbonate Fuel Cells

Molten carbonate fuel cells use carbonate salts of alkali metals as electrolyte. Due to the highly corrosive nature of the electrolyte, various countermeasures are being developed. MCFCs are expected for high-efficiency power generation systems using hydrocarbon fuels, such as natural gas and coal gas. This article describes the mechanisms of operation and cell degradation, as well as the featu...

متن کامل

CO2 Capture by Dual Hollow Fiber Membrane Systems

In this paper, a system for efficient removal of carbon dioxide by hollow fiber membranes is proposed. The system is compact, and it is very useful for application in the offshore energy industries. In particular, it is used to removing CO2 from the exhaust of power generation facilities on offshore platforms.The proposed dual membrane contactor contains two types of membranes (polypropylene me...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Journal of Membrane Science

سال: 2022

ISSN: ['1873-3123', '0376-7388']

DOI: https://doi.org/10.1016/j.memsci.2022.120421